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The “Butterfly Effect” stud and his “Charlie’s Angels” hottie wife looked to be enjoying themselves at the event, held at Ballou Senior High School in Washington DC.

Mr. Kutcher has been doing some work for the President-elect via a collaboration between MySpace and his Katalyst Films company. Per a LA Times report, Ashton and Demi have gathered fellow celebrities to “recruit users to pledge service to Obama by recording videos of their pledges and uploading them to MySpace.”

Talking about where the idea came from, Kutcher told press, “My wife and I, since we met, had been looking for a charitable cause that we can stand in front of. We’ve stood behind a bunch of them, but we wanted to do something where we could make a quantifiable change in the world. Someone came into our office and had the idea of doing pledges for Obama and instantly it was like, ‘We have to do this.’”

He continued, “The first thing you do is set a goal. Then you have to say it out loud to make yourself accountable. That may be one of the only positive aspects of the ego, is that once you say something, your ego sort of forces you to back it up. There will be a site on MySpace that will let users upload videos of themselves making their pledge and have communities organized around actionable causes. Then you go and do what you say you’re going to do. It’s that simple.”